pH Electrodes
ELIT P11 · ELIT P2011
pH is the single most fundamental measurement in aqueous chemistry — and for good reason. From buffer calibration and drinking water compliance through to bioreactor control and soil analysis, virtually every electrochemical workflow begins here. ELIT combination pH electrodes integrate the pH-sensing glass membrane and Ag/AgCl reference system into a single body, giving you a compact, easy-to-use probe that works with any conventional pH meter or directly with ELIT computer interfaces for fully automated logging. Two models are available: the glass-bodied ELIT P11 (ceramic junction, up to 80 °C) and the epoxy-bodied ELIT P2011 (Teflon junction, up to 60 °C).
Glass membrane selective for hydrogen ions with an integrated Ag/AgCl reference system in a single body — the standard configuration for all pH work.
Key Features
- Glass membrane selective for hydrogen ions
- Integrated Ag/AgCl reference system (refillable)
- Accurate and reproducible measurements
- Fast response
- 100% compatible with conventional pH meters AND ELIT computer interfaces
- Maximum performance with ELIT Ion Analysers
| Model | Body | Junction | Temp Range |
|---|---|---|---|
| ELIT P11 | Glass | Annular ceramic | 0–80 °C |
| ELIT P2011 | Epoxy | Porous Teflon | 0–60 °C |
Both models: pH range 0–14 · Dimensions 120 mm × 12 mm · Refillable liquid electrolyte · BNC connector
Store in pH 4 buffer or KCl solution — never dry.
Rinse with deionised water between measurements.
If accidentally dried, soak in pH 4 buffer for 1–2 hours to re-hydrate the glass membrane.
Redox (ORP) Electrodes
ORP-31C · ORP-32C · ORP-33C
Oxidation-reduction potential (ORP) measures a solution's capacity to oxidise or reduce — expressed in millivolts rather than concentration units. A strongly positive reading indicates an oxidising environment (e.g. effectively chlorinated water or well-aerated fermentation); a negative reading indicates reducing conditions (e.g. anaerobic zones or polluted wastewater). Three models are available — ORP-31C (general use), ORP-32C (more demanding applications), and ORP-33C (high precision) — all with platinum sensing elements and Ag/AgCl references for fast, stable mV measurements. Temperature range 0–80 °C, dimensions 12 × 120 mm with 1 m cable and BNC connector.
Measures the oxidation-reduction potential in millivolts — indicating the oxidising or reducing capability of a solution. Critical for disinfection control, environmental monitoring, and process chemistry.
Model Variants
| Model | Application | Pt Element | Body / Junction |
|---|---|---|---|
| ORP-31C | General use | Platinum rod | Gel plastic · Fiber/Pellon SJ |
| ORP-32C | More demanding | Platinum band (glass dome) | Gel plastic · Fiber/Pellon SJ |
| ORP-33C | High precision | Platinum band (glass dome) | Refillable glass · Ceramic SJ |
Operating Procedure
- 1Remove protective bottle from sensing element; rinse with deionised water.
- 2Connect to analyser or meter (set to ORP/mV mode).
- 3Immerse in sample; record stable reading and temperature.
Checking Electrode Operation
Immerse in pH 7 solution saturated with Quinhydrone — stable reading should be 86 ± 15 mV. Then in pH 4 with Quinhydrone — the difference (E₂ − E₁) should be > 165 mV.
Maintenance
- Rinse with deionised water between measurements; long-term storage in soaking solution.
- Non-organic contamination: soak in 0.1 M HCl for 10 minutes.
- Organic/oily contamination: 15 min in dilute detergent (0.1–0.5% hot water), then soak in pH 4 buffer for at least 8 hours before use.
May give unstable readings in solutions containing chromous, vanadous, or titanous ions (strong reducers).
The Ag/AgCl reference can clog in solutions containing silver-complexing agents (TRIS buffer, proteins, sulfides).
Dissolved Oxygen Sensors
Amperometric / Membrane
Dissolved oxygen is one of the most important indicators of aquatic ecosystem health — and a critical control parameter in aquaculture, wastewater treatment, and bioprocess engineering. Low DO signals biological stress in fish ponds, poor treatment efficiency in activated sludge systems, and anaerobic drift in fermenters. ELIT amperometric membrane sensors use an oxygen-permeable membrane and electrochemical cell to give continuous, reliable DO readings in mg/L or % saturation, forming the core of the ELIT 9705b and 9705c Aqualyser systems.
Measures dissolved oxygen concentration in mg/L or % saturation. A core sensor in the ELIT Aqualyser systems and multi-parameter water quality setups.
Technical Notes
- Used in the Aqualyser 9705b as the standard sensor
- Compatible with ELIT multi-channel computer interfaces
- Barometric pressure affects saturation — note local altitude for field use
- Requires periodic membrane and electrolyte replacement
Calibration Requirements
- Calibrate against air-saturated water or zero oxygen standard
- Temperature compensation is essential — oxygen solubility is highly temperature-dependent
- Flow or stirring required for accurate readings (oxygen is consumed at the membrane)
Aqualyser Compatibility
Standard DO sensor for the ELIT 9705b Aqualyser. The extended 9705c version adds ion concentration and conductivity measurement for comprehensive water profiling.
Conductivity Cells
mS/cm & µS/cm range
Electrical conductivity measures the total dissolved ion load in a solution — giving a fast, non-specific snapshot of overall water quality or process stream concentration without identifying individual species. It is one of the most cost-effective parameters to monitor routinely, and pairs naturally with ISE measurements: conductivity flags when something has changed, and ISEs tell you what. ELIT conductivity cells are available in three cell constants to cover the full range from ultrapure laboratory water through to concentrated industrial and environmental samples.
Measures total dissolved ions in solution — a fast, reliable indicator of overall water quality. Three cell constants available to cover the full range from ultrapure water to concentrated industrial solutions.
Cell Types Available
| Type | Cell Constant |
|---|---|
| Low range — pure/deionised water | K ≈ 0.1 |
| Medium range — drinking water, environmental | K ≈ 1.0 |
| High range — industrial, concentrated solutions | K ≈ 10 |
Note: Conductivity measures ALL ions collectively — it does not identify individual species. Use in combination with ISEs for comprehensive water analysis.
Temperature coefficient is typically 2% per °C — temperature compensation is essential for accurate results.
Temperature Sensors
Solid-state, 1 m cable, mini-jack
Temperature is not simply another parameter — it is a correction factor for every other electrochemical measurement you make. The Nernst equation slope, oxygen solubility, and the conductivity temperature coefficient are all strongly temperature-dependent, so even a 3–5 °C difference between your calibration standards and samples can introduce meaningful error. The ELIT solid-state temperature probe plugs directly into any ELIT computer interface via mini-jack, enabling automatic temperature compensation without any additional software configuration.
Designed specifically for use with ELIT computer interfaces. Plugs directly into the mini-jack input to enable automatic temperature compensation for ISE, pH, ORP, and conductivity measurements.
Features
- Mini-jack connector for direct plug-in to ELIT interfaces
- 1 metre cable for immersion flexibility
- Fast response time
- Solid-state design — no fragile glass components
Why Temperature Matters for ISE
The Nernst equation slope is temperature-dependent: 59.2 mV/decade at 25 °C for monovalent ions. A 10 °C difference changes the slope by approximately 2 mV/decade.
Standards and samples should match within ±2 °C, or automatic temperature compensation must be applied. ELIT computer interfaces perform this compensation automatically when the temperature sensor is connected.
Reference Electrodes
ELIT 001 · 002 · 003n
Every ISE and pH measurement requires a reference electrode to complete the electrochemical cell — providing the stable, known potential against which your sensing electrode is measured. The choice of reference matters: the wrong filling solution can react with your sample, clog the junction, or introduce contaminating ions that interfere with your analyte. ELIT offers three Ag/AgCl reference electrodes with different outer filling solutions — select the one that suits your sample chemistry, and replace only the reference if it degrades rather than replacing the entire electrode assembly.
All ELIT reference electrodes have PVC bodies with gel electrolytes. Leak rates are very low; electrolytes do not require replacing under normal use. Must be used with ELIT Electrode Heads (below).
Electrode Heads
ELIT 201 and variants
The electrode head is the practical hub of every ELIT ISE setup — and an often-overlooked component that makes a real difference to both measurement quality and running costs. Rather than requiring each electrode to carry its own expensive high-impedance cable, the electrode head provides a central mounting assembly with gold-plated, shielded connections that hold the ISE and reference electrode together, route both signals to the analyser, and allow individual elements to be swapped out independently. If your reference fails, replace only the reference; the ISE — usually the higher-value component — stays in service.
The electrode head is the practical hub of every ELIT ISE system. It holds the ISE and reference electrode(s) together with gold-plated, low-noise connectors — simplifying operation, reducing cost, and improving data quality.
Why Electrode Heads Matter
- Gold-plated sockets for low-noise, high-impedance connections
- Connect multiple electrodes in a single, easy-to-handle assembly
- If the reference element fails, replace just the reference — not the ISE
- No need for each electrode to carry its own expensive individual cable
Variants Available
| Sockets | Configuration |
|---|---|
| 1 | One sensor, with conventional separate reference |
| 2 | Standard ISE setup — 1 reference + 1 ISE (ELIT 201)Standard |
| 3 | 1 reference + 2 ISEs for simultaneous measurement |
| 7 | 1 reference + 6 ISEs for multi-channel work |
Complete ISE Measurement System
Not sure where to start? A complete ELIT ISE system needs just four components: the ion-selective electrode for your target analyte, a reference electrode, an electrode head to mount them together, and a computer interface or ion meter to read the signal. The table below shows a typical single-channel setup with indicative pricing — add a temperature sensor for automatic compensation, or step up to a multi-channel interface if you need to monitor several ions simultaneously.
| Component | Price |
|---|---|
| Ion Selective Electrode | £180 |
| Reference Electrode (ELIT 003n) | £95 |
| Electrode Head (ELIT 201) | £45 |
| Ion Analyser / Interface (ELIT 9700) | £540 |
| Total system | from £860 |
Prices exclude VAT and shipping. A temperature sensor (£50) is recommended to enable automatic temperature compensation.
If you already have a compatible pH/mV meter, a standalone sensor assembly (ISE + Reference + Electrode Head) is available from £320. ELIT ISEs are 100% compatible with conventional pH/mV meters.
All prices shown exclude VAT and delivery. UK orders are subject to 20% VAT at checkout.